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HomeChemical MartCOLOURING AGENTS USED IN FOOD PRODUCTS

COLOURING AGENTS USED IN FOOD PRODUCTS

ARTICLE BY,
Ass. Prof.  MS Rathore, Richa Sood
CT Institute Of Pharmaceutical Sciences, Jalandhar.

Abstract

Food colorants have been much important in food product manufacturing. Food and color additives are strictly studied, regulated and monitored. Federal regulations require evidence that each substance is safe at its intended level of use before it may be added to foods. Furthermore, all additives are subject to ongoing safety review as scientific understanding and methods of testing continue to improve. A color additive is any dye, pigment or substance which when added or applied to a food, drug or cosmetic, or to the human body, is capable (alone or through reactions with other substances) of imparting color. FDA is responsible for regulating all color additives to ensure that foods containing color additives are safe to eat, contain only approved ingredients and are accurately labeled. Certified colors are synthetically produced (or human made) and used widely because they impart an intense, uniform color, are less expensive, and blend more easily to create a variety of hues. Color is added to food for one or more of the following reasons:
(1) to replace color lost during processing,
(2) to enhance color already present,
(3) to minimize batch-to batch variations, and
(4) to color otherwise uncolored food.

Introduction  

A coloring is any substance that is added to change formulation color. One of the most obvious ways to influence the way a product looks is to add coloring agents. These range from “natural” and artificial colors to washes that enhance browning.
Food colors fall into two main categories: artificial and natural, respectively.

From a regulatory standpoint, natural colors cannot legally be termed natural colors on a food label unless they are used to color the same type of product. For example, beet juice is really only a natural color if it is used to colour beets. If it colours cherry juice, it is technically considered to be artificially coloured and the beet juice is deemed a colour additive. 

Natural Colourings
A growing number of natural food colourings are being commercially produced, partly due to consumer concerns surrounding synthetic colourings. Some examples include:

  • Caramel coloring, made from caramelized sugar, used in cola products and also in cosmetics.
  • Annatto, a reddish-orange dye made from the seed of the Achiote.
  • A green dye made from chlorella algae.
  • Cochineal, a red dye derived from the cochineal insect, Dactylopius coccus.
  • Betanin extracted from beets.
  • Turmeric
  • Saffron
  • Paprika
  • Elderberry

To ensure reproducibility, the coloured components of these substances are often provided in highly purified form, and for increased stability and convenience, they can be formulated in suitable carrier materials (solid and liquid).

Artificial colouring
The colours below are known as “Primary Colours”, when they are mixed to produce other colours, those colours are then known as “Secondary Colours”.

*Brilliant Blue, E133 (Blue shade)
* Indigotine, E132 (Dark Blue shade)
* Fast Green, E143 (Bluish green shade)
* Allura Red AC, E129 (Red shade)
* Erythrosine, E127 (Pink shade)
* Tartrazine, E102 (Yellow shade)
* Sunset Yellow, E110 (Orange shade)

Dyes and Lakes
Colour additives are available for use in food as either “dyes” or “lakes”.
Dyes dissolve in water, but are not soluble in oil. Dyes are manufactured as powders, granules, liquids or other special purpose forms. They can be used in beverages, dry mixes, baked Goods, confectionry, dairy products, pet foods and a variety of other products.
Lakes are the combination of dyes and insoluble material. Lakes tint by dispersion. Lakes are not oil soluble, but are oil dispersible. Lakes are more stable than dyes and are ideal for colouring products containing fats and oils or items lacking sufficient moisture to dissolve dyes. Typical uses include coated tablets, cake and donut mixes, hard candies and chewing gum.

Artificial colours consist of water soluble synthetic dyes or the aluminum salts of these dyes, called “Lakes.” These seven synthetic dyes and their salts are deemed acceptable by most Food authorities for use in food. Blending the seven produces a wide spectrum of colour, including purple, black, brown, and variations of the primary colours.

Dyes display colours when dissolved in the aqueous phase of a food product. However, their solubility varies with temperature and often with the solute. Although at typical usage levels this will not ordinarily affect the finished product, it could make a difference when colour solutions are prepared. If the temperature of the solute changes, all the dye may not be in solution, and this could affect the colour of the finished product.

The Lakes are insoluble in most solvents and instead colour by dispersion. They are used in low moisture, often high-fat applications, but are not fat soluble. They may bleed color slightly in water, but in most applications they minimize colour bleed into adjoining areas. The shades produced depend on the method of production and to some extent on particle size. Lakes are more resistant than dyes to fading when exposed to high heat and light. Dyes go into solution and function on a molecular level. Lakes are different because the particles are dispersed. Particle size, particle shape and how well the particles are dispersed in the finished product all influence the outcome. In some cases, simply increasing the shear during dispersion may intensify the colour.

ARTIFICIAL COLOURANTS-

colouring
agent
descriptioncolourodourstability
to light
oxidationpH
ErythrosineSolid, fine powderRedodorless poorfair8-10
Sunset Yellow

Solid, fine
powder
Reddish
Orange
odorless Goodfair6-8
tartrazineSolid, fine
powder
Light orangeodorless Goodfair6-8
PonceauSolid, fine
powder
Redodorless Goodfair6-8
Allura  red

Solid, fine
powder
Deep redodorlessVery
good
fair6-8
amaranthSolid, fine
powder
Reddish brownodorlessGoodpoor6-8
Indigo carmineSolid, fine powderBluish brownodorless Very
poor
poor6-7
Brilliant blueSolid, fine
powder
Bluish violetodorlessGoodpoor6-7
Quinoline yellowObtained from coal tarYellow  to orange powderTar-like odourfairForms quinolinic acid8-9

NATURAL COLOURANTS-

Colouring agentDescriptionColourOdourStability to lightOxidationpHDensitySolubility
PaprikaClear dark red oily liquid,DarkredOdorlessstablepoor4.60.935-0.945Soluble in fats and oil
AnnattoCrystalline powderBright Yellow To Orange redPeculiar odourFades inStrong&Direct lightDegrades By oxidation5.50.6Soluble in alcohol, ether,oils
CaramelThick liquidDark brownPleasentstablestable2-100.6-0.7Soluble in water ,dilute alcohol.Insoluble in benzene, chloroform, ether
CarotenePowder, crystalsRed to Brownstablestable2-14Soluble in carbon disulphide, benzene, chloroform.Sparingly soluble in methanol and ethanol.Insoluble in water,acid,alkali.
CurcuminCrystal formOrange yellowOdorlessDegradationOccurs with ferrous oxide8-9Low densityAlcohol>Acetic acid
RiboflavinFine powder in needle formWhitish yellowSlightlyOdorlessLight resistantDark at 240 degree4.5-7highEthanol>water>cyclohexane
CarminePowder formBright redOdorlessStableOxidation changes blue to purple colour
11.4-13
True bulk densitySoluble in ethanol.Insoluble in water.
CurcuminCrystal formOrange yellowOdorlessDegradationOccurs with ferrous oxide8-9Low densityAlcohol>Acetic 

SOURCE:

SOURCE:https://www.pharmatutor.org/articles/colouring-agents-used-in-food-products

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